Well, there's your problem. You don't need any strange minerals in the cave, just a bit of salt water. Aluminium has a higher electrode potential than zinc, so just like with chrome over steel, if you scratch it the aluminium will start to corrode in preference to the zinc. The salt has a dual role - providing a conductive path to complete the circuit, and breaking up the oxide layers on the zinc and aluminium to allow the corrosion to penetrate. |